dc.contributor.authors |
Kumar, B. Arjun; Ramalingam, G.; Rangasamy, Baskaran; Lahiri, Abhishek; Somaily, H. H.; Alzahrani, Jamila S.; Al-Buriahi, M. S. |
|
dc.date.accessioned |
2022-12-20T13:25:28Z |
|
dc.date.available |
2022-12-20T13:25:28Z |
|
dc.date.issued |
2022 |
|
dc.identifier.issn |
0957-4522 |
|
dc.identifier.uri |
http://dx.doi.org/10.1007/s10854-022-08084-1 |
|
dc.identifier.uri |
https://hdl.handle.net/20.500.12619/99342 |
|
dc.description |
Bu yayının lisans anlaşması koşulları tam metin açık erişimine izin vermemektedir. |
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dc.description.abstract |
Pseudo-capacitors are the emerging energy storage devices which forms a bridge between batteries and conventional capacitors. In the present work, alpha-Mn2O3 nanorods have been synthesized by one-pot acid-assisted hydrothermal method for supercapacitor applications. The alpha-Mn(2)O(3)nanorod electrode is characterized by X-ray diffraction, SAED, Transmission Electron Microscopy (TEM), EDX and tested for supercapacitor application. XRD results indicate polycrystalline nature of alpha-Mn2O3. TEM results reveal an optimum nanorod diameter of 7 nm and length of 100 nm with high aspect ratio of 1:4. The high aspect ratio obtained by acid assisted one-pot hydrothermal route and the possible growth mechanism are explored. The structural and morphological investigations reveal that the acid implementation and suitable reaction temperature plays a crucial factor in the formation of homogeneous alpha-Mn2O3 nanorods. The cyclic voltammetry redox kinetics indicates pseudo-capacitive behavior with an excellent specific capacitance of 1377 F g(-1) at 5 mVs(-1). The galvanostatic charge-discharge investigations reveal an excellent 69% capacitance retention even after 1000 cycles. Ex-situ SEM, XRD and impedance spectroscopy investigations have been carried out to understand the nature of alpha-Mn2O3 nanorod after 1000 cycles. The synergetic effect of nanorod architecture, nanoparticle presence has been discussed in terms of excellent supercapacitive behavior. |
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dc.language |
English |
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dc.language.iso |
eng |
|
dc.relation.isversionof |
10.1007/s10854-022-08084-1 |
|
dc.subject |
Engineering |
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dc.subject |
Materials Science |
|
dc.subject |
Physics |
|
dc.title |
Enhanced alpha-Mn2O3 nanorods synthesized by one-pot hydrothermal route for supercapacitors |
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dc.contributor.authorID |
Rangasamy, Baskaran/0000-0002-6677-5381 |
|
dc.contributor.authorID |
Somaily, Hamoud/0000-0002-1441-3493 |
|
dc.contributor.authorID |
Bojarajan, ArjunKumar/0000-0001-5159-2833 |
|
dc.identifier.volume |
33 |
|
dc.identifier.startpage |
11067 |
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dc.identifier.endpage |
11077 |
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dc.relation.journal |
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS |
|
dc.identifier.issue |
14 |
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dc.identifier.doi |
10.1007/s10854-022-08084-1 |
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dc.identifier.eissn |
1573-482X |
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dc.contributor.author |
Kumar, B. Arjun |
|
dc.contributor.author |
Ramalingam, G. |
|
dc.contributor.author |
Rangasamy, Baskaran |
|
dc.contributor.author |
Lahiri, Abhishek |
|
dc.contributor.author |
Somaily, H. H. |
|
dc.contributor.author |
Alzahrani, Jamila S. |
|
dc.contributor.author |
Al-Buriahi, M. S. |
|
dc.relation.publicationcategory |
Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı |
|