dc.date.accessioned |
2021-06-08T09:11:15Z |
|
dc.date.available |
2021-06-08T09:11:15Z |
|
dc.date.issued |
2020 |
|
dc.identifier.issn |
0379-6779 |
|
dc.identifier.uri |
https://hdl.handle.net/20.500.12619/95797 |
|
dc.description |
This work was supported by the Research Fund of Sakarya University (Project no: 2016-50-02-008 and 2015-02-04-001). E. Guzel wishes to thank Assoc. Prof. Dr. M. Salome Rodriguez-Morgade and Prof. Dr. Tomas Torres from Autonoma University of Madrid for their excellent laboratory facilities and helpful discussions. A.R. Ozkaya thanks Turkish Academy of Sciences (TUBA) for partial financial support. |
|
dc.description |
Bu yayının lisans anlaşması koşulları tam metin açık erişimine izin vermemektedir. |
|
dc.description.abstract |
In this work, metal-free and metallo porphyrazine/phthalocyanine hybrids (3a-5b) containing unsymmetrical tert-butyl phenyl and electron withdrawing -NO2 functional groups have been synthesized firstly by direct condensation technique instead of statistical condensation from substituted donor and acceptor precursors; 3,4-Bis(4-tert-butylphenyl)pyrroline-2,5-diimine (1) and 6,7-nitro-1,3,3-tricholoroisoindoline (2). The complexes were characterized by elemental analysis, FT-IR, H-1-NMR, UV-vis and MALDI-TOF spectroscopy. Electrochemical and in situ spectroelectrochemical measurements of the complexes revealed that the attachment of NO2 moieties at the periphery makes a monitorable effect on their redox properties in comparison with those of similar phthalocyanine compounds. |
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dc.description.sponsorship |
Research Fund of Sakarya UniversitySakarya University [2016-50-02-008, 2015-02-04-001]; Turkish Academy of Sciences (TUBA)Turkish Academy of Sciences |
|
dc.language |
English |
|
dc.language.iso |
eng |
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dc.publisher |
ELSEVIER SCIENCE SA |
|
dc.relation.isversionof |
10.1016/j.synthmet.2020.116331 |
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dc.rights |
info:eu-repo/semantics/closedAccess |
|
dc.subject |
SINGLET OXYGEN GENERATION |
|
dc.subject |
SECO-PORPHYRAZINES |
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dc.subject |
PHTHALOCYANINES |
|
dc.subject |
ZINC |
|
dc.subject |
COORDINATION |
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dc.subject |
SUBSTITUENTS |
|
dc.subject |
AGGREGATION |
|
dc.subject |
CHEMISTRY |
|
dc.title |
Low symmetry solitaire- and trans-functional porphyrazine/phthalocyanine hybrid complexes: Synthesis, isolation, characterization, and electrochemical and in-situ spectroelectrochemical properties |
|
dc.type |
Article |
|
dc.contributor.authorID |
Guzel, Emre/0000-0002-1142-3936 |
|
dc.identifier.volume |
262 |
|
dc.relation.journal |
SYNTHETIC METALS |
|
dc.identifier.doi |
10.1016/j.synthmet.2020.116331 |
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dc.contributor.author |
Guzel, Emre |
|
dc.contributor.author |
Yarasir, M. Nilufer |
|
dc.contributor.author |
Ozkaya, Ali Riza |
|
dc.relation.publicationcategory |
Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı |
|