A water-soluble multisite ionophore ligand bearing pyridine and aminothiophenol functionality. Synthesis, spectroscopy and electrochemistry of its complexes, and peripheral reactivity of the (E,E)M (M = Ni) complex with Pd2+ and Ag+

Kandaz, Mehmet

dc.contributor.authors	Kandaz, M; Ozkaya, AR; Koca, A;
dc.date.accessioned	2020-02-24T14:22:46Z
dc.date.available	2020-02-24T14:22:46Z
dc.date.issued	2004
dc.identifier.citation	Kandaz, M; Ozkaya, AR; Koca, A; (2004). A water-soluble multisite ionophore ligand bearing pyridine and aminothiophenol functionality. Synthesis, spectroscopy and electrochemistry of its complexes, and peripheral reactivity of the (E,E)M (M = Ni) complex with Pd2+ and Ag+. TRANSITION METAL CHEMISTRY, 29, 854-847
dc.identifier.issn	0340-4285
dc.identifier.uri	https://hdl.handle.net/20.500.12619/45345
dc.identifier.uri	https://link.springer.com/content/pdf/10.1007/s11243-004-1567-8.pdf
dc.description.abstract	The design, synthesis and coordination of a novel multisite vic-dioxime compound, LH2 containing flexible pyridine substituents and amitiophcnylsulfanyl moieties on the periphery, facilitating solubility in water as pyridinium hydrochloride salt are described. LH2 was prepared by the reaction between 2-(2-pyridylethylamino)-benzenethiol and (E,E)-dichloroglydioxime. Mononuclear [(E,E)M] (M = Ni-II, Cu-II. Co-II, Fe-II and Mn-II) and dinuclear uranyl (UO2II) complexes of LH2 were isolated and characterized with metal:ligand ratios of 1:2 and 2:2. respectively. The reaction of Na2PdCl4 . 3H(2)O and AgNo3 in DMF with the mononuclear complex, (LH)(2)Ni, resulted in the formation of the heterotrinuclear complexes [Pd2Ni(LH)(2)]Cl-4 and [Ag2Ni(LH)(2)](NO3)(2). The complexes were characterized by elemental analysis, H-1-n.m.r., u.v.-vis. spectroscopy, i.r., and MS (LSIMS). The redox properties of the complexes were studied by cyclic voltammetry.
dc.language	English
dc.publisher	KLUWER ACADEMIC PUBL
dc.subject	Chemistry
dc.title	A water-soluble multisite ionophore ligand bearing pyridine and aminothiophenol functionality. Synthesis, spectroscopy and electrochemistry of its complexes, and peripheral reactivity of the (E,E)M (M = Ni) complex with Pd2+ and Ag+
dc.type	Article
dc.identifier.volume	29
dc.identifier.startpage	847
dc.identifier.endpage	854
dc.contributor.department	Sakarya Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü
dc.contributor.saüauthor	Kandaz, Mehmet
dc.relation.journal	TRANSITION METAL CHEMISTRY
dc.identifier.wos	WOS:000226417200004
dc.contributor.author	Kandaz, Mehmet