Peripherally and non-peripherally tetra-HBME (4-hydroxybenzyl methyl ether) substituted metal-free and zinc(II) phthalocyanines: Synthesis, characterization, and investigation of photophysical and photochemical properties

Günsel, Armağan; Sevde Beylik; Bilgiçli, Ahmet Turgut; Goknur Yasa Atmaca; Ali Erdogmus; Yaraşır, Meryem Nilüfer

dc.contributor.authors	Gunsel, A; Beylik, S; Bilgicli, AT; Atmaca, GY; Erdogmus, A; Yarasir, MN;
dc.date.accessioned	2020-02-24T14:20:13Z
dc.date.available	2020-02-24T14:20:13Z
dc.date.issued	2018
dc.identifier.citation	Gunsel, A; Beylik, S; Bilgicli, AT; Atmaca, GY; Erdogmus, A; Yarasir, MN; (2018). Peripherally and non-peripherally tetra-HBME (4-hydroxybenzyl methyl ether) substituted metal-free and zinc(II) phthalocyanines: Synthesis, characterization, and investigation of photophysical and photochemical properties. INORGANICA CHIMICA ACTA, 477, 205-199
dc.identifier.issn	0020-1693
dc.identifier.uri	https://doi.org/10.1016/j.ica.2018.03.026
dc.identifier.uri	https://hdl.handle.net/20.500.12619/45223
dc.description.abstract	This paper reports on the synthesis and characterization of non-peripherally and peripherally tetrasubstituted metal-free and zinc(II) phthalocyanines functionalized with the phenolic compound "4-hydroxy-benzyl methyl ether (HBME)". Synthesized compounds have been characterized by elemental analysis, FT-IR, H-1 NMR, C-13 NMR, MALDI-MS and UV-Vis spectral data. Besides, spectral, photophysical (fluorescence quantum yields and lifetimes) and photochemical (singlet oxygen generation and photodegradation under light irradiation) properties of newly synthesized phthalocyanines were investigated in DMF solution. We obtained very high singlet oxygen quantum yields as 0.86, 0.91, suggesting its potential as photosensitizer in PDT treatment. (C) 2018 Elsevier B.V. All rights reserved.
dc.language	English
dc.publisher	ELSEVIER SCIENCE SA
dc.subject	Chemistry
dc.title	Peripherally and non-peripherally tetra-HBME (4-hydroxybenzyl methyl ether) substituted metal-free and zinc(II) phthalocyanines: Synthesis, characterization, and investigation of photophysical and photochemical properties
dc.type	Article
dc.identifier.volume	477
dc.identifier.startpage	199
dc.identifier.endpage	205
dc.contributor.department	Sakarya Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü
dc.contributor.saüauthor	Günsel, Armağan
dc.contributor.saüauthor	Bilgiçli, Ahmet Turgut
dc.contributor.saüauthor	Yaraşır, Meryem Nilüfer
dc.relation.journal	INORGANICA CHIMICA ACTA
dc.identifier.wos	WOS:000429902200027
dc.identifier.doi	10.1016/j.ica.2018.03.026
dc.identifier.eissn	1873-3255
dc.contributor.author	Günsel, Armağan
dc.contributor.author	Sevde Beylik
dc.contributor.author	Bilgiçli, Ahmet Turgut
dc.contributor.author	Goknur Yasa Atmaca
dc.contributor.author	Ali Erdogmus
dc.contributor.author	Yaraşır, Meryem Nilüfer