Açık Akademik Arşiv Sistemi

(E, E)S, S '-bis(2-benzimidazolylmethyl) dithioglyoxime, synthesis and characterization of heterotrinuclear complexes of and determination of their metal contents by EDXRF analysis

Show simple item record

dc.contributor.authors Yildiz, SZ; Cevik, U; Atalay, Y;
dc.date.accessioned 2020-01-20T08:01:55Z
dc.date.available 2020-01-20T08:01:55Z
dc.date.issued 2008
dc.identifier.citation Yildiz, SZ; Cevik, U; Atalay, Y; (2008). (E, E)S, S '-bis(2-benzimidazolylmethyl) dithioglyoxime, synthesis and characterization of heterotrinuclear complexes of and determination of their metal contents by EDXRF analysis. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 693, 196-189
dc.identifier.issn 0022-328X
dc.identifier.uri https://hdl.handle.net/20.500.12619/31941
dc.identifier.uri https://doi.org/10.1016/j.jorganchem.2007.10.019
dc.description.abstract A vicinal dioxime ligand with two 2-benzimidazolylmethyl groups, namely S,S'-bis(2-benzimidazolylmethyl) dithioglyoxine (H2L) and its axially pyridine and 2,6-dimethyl pyridine bonded Co(III) complexes were prepared according to prior literature [Y. Gok, S.Z. Yildiz, Synth. React. Inorg. Met-Org. Chem. 22 (9) (1992) 1327]. BF2+ bridged Co(111) complexes have been synthesized via the hydrogen-bridged Co(111) complexes by using borontrifloride ethyl ether complex. Heterotrinuclear complexes have been prepared by the reaction of these more soluble BF2-capped Co(III) complexes with stoichiometric amount of CdCl2 center dot H2O and NiCl2 center dot 6H(2)O salts. Using H-1, C-13 NMR, IR and MS spectral data and elemental analysis, the structures of the complexes were identified. Qualitative and quantitative determination of Co, Ni and Cd contents of the heterotrinuclear complexes have been investigated by energy dispersive X-ray fluorescence (EDXRF) method. An annular 50 mCi(241) Am radioactive source emitting 59.543 keV photons was used for excitation and Si(Li) detector having 157 eV FWHM at 5.9 keV was used for intensity measurements. (C) 2007 Elsevier B.V. All rights reserved.
dc.language English
dc.publisher ELSEVIER SCIENCE SA
dc.subject Chemistry
dc.title (E, E)S, S '-bis(2-benzimidazolylmethyl) dithioglyoxime, synthesis and characterization of heterotrinuclear complexes of and determination of their metal contents by EDXRF analysis
dc.type Article
dc.identifier.volume 693
dc.identifier.startpage 189
dc.identifier.endpage 196
dc.contributor.department Sakarya Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü
dc.contributor.saüauthor Yıldız, Salih Zeki
dc.contributor.saüauthor Atalay, Yusuf
dc.relation.journal JOURNAL OF ORGANOMETALLIC CHEMISTRY
dc.identifier.wos WOS:000252686800002
dc.identifier.doi 10.1016/j.jorganchem.2007.10.019
dc.identifier.eissn 1872-8561
dc.contributor.author Yıldız, Salih Zeki
dc.contributor.author Atalay, Yusuf


Files in this item

Files Size Format View

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record