Periferal konumlarda dört tane (E)-1-(furan-2-yl)-3-(4-hydroxyphenyl)prop-2-en-1-one çalkon grubu taşıyan yeni metalli ftalosiyaninler (M = Zn, Co) sentezlendi. Bu kompleksler FT-IR, 1H-NMR, HRMS ve UV–Vis spektroskopi teknikleri kombinasyonu ile karakterize edildi. Ayrıca bu ftalosiyaninlerin siklik voltamogramları alındı ve çinko ftalosiyanin için bir, kobalt ftalosiyanin için iki redüksiyon reaksiyonu olduğu bilgisi elde edildi. Spektroelektrokimyasal incelemeler metalli ftalosiyaninlerin halka merkezli indirgenme potansiyelini gösterir. Anahtar kelimeler: Çalkon, ftalosiyanin, metalli ftalosiyanin, UV-Visible elektrokimya, siklik voltamogram
Novelmetallophthalocyanines (M = Zn, Co) carrying on thefour of the peripheral positions (E)-1-(furan-2-yl)-3-(4-hydroxyphenyl)prop-2-en-1-one as chalcone were sythesized. These complexes have been characterized by a combination of FT-IR, 1H-NMR, HRMS and UV–Vis spectroscopy techniques. Also cyclic voltammograms of these phthalocyanines were taken and obtained knowledge as zinc phthalocyanine have one reduction reaction and cobalt phthalocyanine have two reduction reaction. Spectroelectrochemical investigation shows the ring based reduction of MPc's. SYNTHESIS AND CHARACTERIZATION OF NOVEL CHALCONE SUBSTITUTED METALLOPHTHALOCYANINES Keywords: Chalcone, phthalocyanine, Metallophthalocyanine, UV-Visible, electrochemistry, cyclic voltammogram
