Synthesis of tetra-substituted metallophthalocyanines: Spectral, structural, computational studies and investigation of their photophysical and photochemical properties

Güzel, Emre; Günsel, Armağan; Burak Tuzun; Goknur Yasa Atmaca; Bilgiçli, Ahmet Turgut; Ali Erdogmus; Yaraşır, Meryem Nilüfer; Yaraşır, Meryem Nilüfer

dc.contributor.authors	Guzel, E; Gunsel, A; Tuzun, B; Atmaca, GY; Bilgicli, AT; Erdogmus, A; Yarasir, MN;
dc.date.accessioned	2020-02-24T14:21:22Z
dc.date.available	2020-02-24T14:21:22Z
dc.date.issued	2019
dc.identifier.citation	Guzel, E; Gunsel, A; Tuzun, B; Atmaca, GY; Bilgicli, AT; Erdogmus, A; Yarasir, MN; (2019). Synthesis of tetra-substituted metallophthalocyanines: Spectral, structural, computational studies and investigation of their photophysical and photochemical properties. POLYHEDRON, 158, 324-316
dc.identifier.issn	0277-5387
dc.identifier.uri	https://doi.org/10.1016/j.poly.2018.10.072
dc.identifier.uri	https://hdl.handle.net/20.500.12619/45281
dc.description.abstract	This work presents the synthesis of peripherally and non-peripherally tetra-substituted metallophthalocyanines (6-14) containing the 2-(3,4-dimethoxyphenyl)ethanol group. The synthesized compounds were characterized by standard spectroscopy methods. The ligands of the metallophthalocyanines were investigated by quantum chemical calculations. The quantum chemical parameters of these ligands (1 and 2) such as the HOMO, LUMO and chemical hardness were calculated by the B3lyp, HF and M062x methods. The Delta G value of the metal complexes of the ligands were calculated with the obtained results. In addition, photophysical (fluorescence quantum yields) and photochemical (singlet oxygen generation and photodegradation under light irradiation) properties of newly synthesized phthalocyanines were investigated in DMSO solutions, comparatively. (C) 2018 Elsevier Ltd. All rights reserved.
dc.language	English
dc.publisher	PERGAMON-ELSEVIER SCIENCE LTD
dc.subject	Crystallography
dc.title	Synthesis of tetra-substituted metallophthalocyanines: Spectral, structural, computational studies and investigation of their photophysical and photochemical properties
dc.type	Article
dc.identifier.volume	158
dc.identifier.startpage	316
dc.identifier.endpage	324
dc.contributor.department	Sakarya Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü
dc.contributor.saüauthor	Güzel, Emre
dc.contributor.saüauthor	Günsel, Armağan
dc.contributor.saüauthor	Bilgiçli, Ahmet Turgut
dc.contributor.saüauthor	Yaraşır, Meryem Nilüfer
dc.contributor.saüauthor	Yaraşır, Meryem Nilüfer
dc.relation.journal	POLYHEDRON
dc.identifier.wos	WOS:000458228500038
dc.identifier.doi	10.1016/j.poly.2018.10.072
dc.contributor.author	Güzel, Emre
dc.contributor.author	Günsel, Armağan
dc.contributor.author	Burak Tuzun
dc.contributor.author	Goknur Yasa Atmaca
dc.contributor.author	Bilgiçli, Ahmet Turgut
dc.contributor.author	Ali Erdogmus
dc.contributor.author	Yaraşır, Meryem Nilüfer
dc.contributor.author	Yaraşır, Meryem Nilüfer