A comprehensive study for selective removal of Cr(VI) by asymmetric imidazolium bromide salts as environmentally-friendly extractant

Abstract

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The study was to determine selective removal and recovery of Cr(VI) from acidic media by solvent extraction (SX) using asymmetric imidazolium-based room temperature imidazolium bromide salts (ARTILs) as the extractants. The relevant parameters on the extraction and the stripping of Cr(VI) were investigated to identify optimum conditions. The optimum conditions were determined as equilibration time 5 minutes, acid concentration and type 0.5 mol/L H2SO4, stirring speed 1200 rpm, extractant concentration and type 0.5 mol/L ARTIL5, phase ratio 2.0 and stripping reagent type, and concentration 2.0 mol/L NH3. In optimum conditions, decyl substituted ARTIL was best in extraction process about 99.7% of extraction rate, whereas moderately hydrophobic pentyl substituted ARTIL was best in stripping process about 70.0% of stripping rate. Also, the optimized process was found as so selective toward Cr(VI) in the presence of the other metal ions with an environmental-friendly liquid–liquid–based SX method.