Trisequential Photooxygenation Reaction: Application to the Synthesis of Carbasugars

Baran, Arif

dc.contributor.authors	Baran, A; Aydin, G; Savran, T; Sahin, E; Balci, M;
dc.date.accessioned	2020-02-24T14:15:57Z
dc.date.available	2020-02-24T14:15:57Z
dc.date.issued	2013
dc.identifier.citation	Baran, A; Aydin, G; Savran, T; Sahin, E; Balci, M; (2013). Trisequential Photooxygenation Reaction: Application to the Synthesis of Carbasugars. ORGANIC LETTERS, 15, 4353-4350
dc.identifier.issn	1523-7060
dc.identifier.uri	https://doi.org/10.1021/ol401823m
dc.identifier.uri	https://hdl.handle.net/20.500.12619/44933
dc.description.abstract	4,5-Dimethylenecyclohex-1-ene was subjected to a photooxygenation reaction to introduce oxygen functionalities. The endoperoxide obtained underwent an ene-reaction to form hydroperoxides with 1,3-diene structures. Further addition of singlet oxygen to the diene units resulted in the formation of tricyclic hydroperoxides having three oxygens in the molecule. Cleavage of the oxygen-oxygen bonds followed by epoxidation of the remaining C-C double bond and concomitant ring-opening reaction furnished the isomeric carbasugars.
dc.language	English
dc.publisher	AMER CHEMICAL SOC
dc.subject	Chemistry
dc.title	Trisequential Photooxygenation Reaction: Application to the Synthesis of Carbasugars
dc.type	Article
dc.identifier.volume	15
dc.identifier.startpage	4350
dc.identifier.endpage	4353
dc.contributor.department	Sakarya Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü
dc.contributor.saüauthor	Baran, Arif
dc.relation.journal	ORGANIC LETTERS
dc.identifier.wos	WOS:000328864800020
dc.identifier.doi	10.1021/ol401823m
dc.identifier.eissn	1523-7052
dc.contributor.author	Baran, Arif