Selective transport of cobalt (II) from ammoniacal solutions containing cobalt (II) and nickel (II) by emulsion liquid membranes using 8-hydroxyquinoline

Abstract

The selective transport of cobalt (II) from ammoniacal solutions containing nickel (II) and cobalt (II) by emulsion liquid membranes (ELMs) using 8-hydroxyquinoline (8-HQ) as extractant has been presented. Membrane solution consists of a diluent (kerosene), a surfactant (ECA 4360J), and an extractant (8-HQ). Very dilute sulphuric solution buffered at pH 5.0 has been used as a stripping solution. The ammoniacal feed solution pH was adjusted to 9.0 with hydrochloric acid. The important variables governing the permeation of cobalt (II) have been studied. These variables are membrane composition, pH of the feed solution, cobalt (II) and nickel (II) concentrations of the feed solution, stirring speed, surfactant concentration, extractant concentration, complexing agent concentration and pH of the stripping solution, and phase ratio. After the optimum conditions had been determined, it was possible to selectively transport 95.0% of cobalt (II) from ammoniacal feed solution containing Co2+ and Ni2+ ions. The separation factors of cobalt (II) with respect to nickel (II), based on initial feed concentration, have experimentally found to be of as high as 31 for equimolar Co(II)-Ni(II) feed solution. (C) 2011 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.