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Synthesis of Bishomoinositols and an Entry for Construction of a Substituted 3-Oxabicyclo[3.3.1]nonane Skeleton

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dc.contributor.authors Baran, A; Bekarlar, M; Aydin, G; Nebioglu, M; Sahin, E; Balci, M;
dc.date.accessioned 2020-02-24T14:15:04Z
dc.date.available 2020-02-24T14:15:04Z
dc.date.issued 2012
dc.identifier.citation Baran, A; Bekarlar, M; Aydin, G; Nebioglu, M; Sahin, E; Balci, M; (2012). Synthesis of Bishomoinositols and an Entry for Construction of a Substituted 3-Oxabicyclo[3.3.1]nonane Skeleton. JOURNAL OF ORGANIC CHEMISTRY, 77, 1250-1244
dc.identifier.issn 0022-3263
dc.identifier.uri https://doi.org/10.1021/jo202494v
dc.identifier.uri https://hdl.handle.net/20.500.12619/44838
dc.description.abstract 1,3,3a,7a-Tetrahydro-2-benzofuran was used as key compound for the synthesis of various bishomoinositol derivatives. The diene was subjected to an epoxidation reaction for further functionalization of the diene unit. The bisepoxide obtained was submitted to a ring-opening reaction with acid in the presence of water. Various bishomoinositols were synthesized. However, when the reaction was carried out in the presence of acetic anhydride, a substituted 3-oxabicyclo[3.3.1]nonane skeleton was formed. The mechanism of the formation of the products is discussed.
dc.language English
dc.publisher AMER CHEMICAL SOC
dc.subject Chemistry
dc.title Synthesis of Bishomoinositols and an Entry for Construction of a Substituted 3-Oxabicyclo[3.3.1]nonane Skeleton
dc.type Article
dc.identifier.volume 77
dc.identifier.startpage 1244
dc.identifier.endpage 1250
dc.contributor.department Sakarya Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü
dc.contributor.saüauthor Baran, Arif
dc.contributor.saüauthor Nebioğlu, Mehmet
dc.relation.journal JOURNAL OF ORGANIC CHEMISTRY
dc.identifier.wos WOS:000300462700003
dc.identifier.doi 10.1021/jo202494v
dc.identifier.eissn 1520-6904
dc.contributor.author Baran, Arif
dc.contributor.author Nebioğlu, Mehmet


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