Selective Separation and Concentration of Pd(II) from Fe(III), Co(II), Ni(II), and Cu(II) Ions Using Thiourea-Formaldehyde Resin

Abstract

Thiourea-formaldehyde (TUF), a well-known chelating resin, has been synthesized and it was used in the adsorption, selective separation, and concentration of Pd(II) ions from Fe(III), Co(II) Ni(II), and Cu(II) base metal ions. The composition of the synthesized resin was determined by elemental analysis. The effect of initial acidity/pH and the adsorption capacity for Pd(II) ions were studied by batch technique. The adsorption and separation of Pd(II) were then examined by column technique. FTIR spectra and SEM/EDS analysis were also recorded before and after the adsorption of Pd(II). The optimum pH was found to be 4 for the adsorption. The adsorption data fitted well to the Langmuir isotherm. The maximum adsorption capacity of the TUF resin for Pd(II) ions was found to be 31.85 mg g(-1) (0.300 mmol g(-1)). Chelating mechanism was effective in the adsorption. Pd(II) ions could be separated efficiently from Fe(III), Cu(II), Ni(II), and Co(II) ions using TUF resin. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 120: 3316-3324, 2011