Metal-free and metallophthalocyanines appending with eight 12-crown-4 ethers

Yıldız, Salih Zeki

dc.contributor.authors	Biyiklioglu, Z; Yildiz, SZ; Kantekin, H;
dc.date.accessioned	2020-02-24T14:14:34Z
dc.date.available	2020-02-24T14:14:34Z
dc.date.issued	2010
dc.identifier.citation	Biyiklioglu, Z; Yildiz, SZ; Kantekin, H; (2010). Metal-free and metallophthalocyanines appending with eight 12-crown-4 ethers. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 695, 1733-1729
dc.identifier.issn	0022-328X
dc.identifier.uri	https://doi.org/10.1016/j.jorganchem.2010.04.014
dc.identifier.uri	https://hdl.handle.net/20.500.12619/44766
dc.description.abstract	The metal-free phthalocyanine 2 was synthesized from the 4,5-bis(1,4,7,10-tetraoxacyclododecan-2-ylmethoxy)phthalonitrile 1 in the presence of a strong base in n-pentanol. The synthesis of metallo derivatives [Ni(II), Co(II), Cu(II)] of phthalocyanines obtained from corresponding phthalonitrile derivative 1 and in the presence of the anhydrous divalent metal salts (NiCl2, CoCl2 and CuCl2) were described. The thermal stabilities of the metal-free and metallophthalocyanines were determined by thermogravimetric analysis. These phthalocyanines were good soluble inorganic solvents such as chloroform, dichloromethane, tetrahydrofuran and DMF. The products were characterized by elemental analysis, IR, H-1 NMR, UV-vis and MS spectral data. (C) 2010 Elsevier B.V. All rights reserved.
dc.language	English
dc.publisher	ELSEVIER SCIENCE SA
dc.subject	Chemistry
dc.title	Metal-free and metallophthalocyanines appending with eight 12-crown-4 ethers
dc.type	Article
dc.identifier.volume	695
dc.identifier.startpage	1729
dc.identifier.endpage	1733
dc.contributor.department	Sakarya Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü
dc.contributor.saüauthor	Yıldız, Salih Zeki
dc.relation.journal	JOURNAL OF ORGANOMETALLIC CHEMISTRY
dc.identifier.wos	WOS:000278562900017
dc.identifier.doi	10.1016/j.jorganchem.2010.04.014
dc.identifier.eissn	1872-8561
dc.contributor.author	Yıldız, Salih Zeki