Separation of Gold(III) Ions from Copper(II) and Zinc(II) Ions Using Thiourea-Formaldehyde or Urea-Formaldehyde Chelating Resins

Abstract

Thiourea-formaldehyde (TF) and urea-formaldehyde (UF) chelating resins were synthesized and these resins were used in the separation of gold(III) ions from copper(H) and zinc(II) base metal ions. In the experimental studies, the effect of acidity on gold(III) uptake and gold(III) adsorption capacities by batch method, and loading and elution profiles of gold(III) ions, gold(III), copper(II), and zinc(II), dynamic adsorption capacities and the stability tests of TF and UF resins by column method were examined. By batch method, the Optimum acidities were found as pH 2 and 0.5M HCl, and gold(III) adsorption capacities in the solutions including copper(IT) and zinc(II) ions were obtained as 0.088 and 0.151 meq Au(III)/g for UF and TF resins, respectively. On the other hand, by column method, the dynamic adsorption capacities were calculated as 0.109 meq Au(III)/g with TF, 0.023 meq Au(III)/g with UF, 0.015 meq Cu(II)/g with TF, 0.0057 meq Cu(II)/g with UF, and under 6.1 x 10(-5) meq Zn(II)/g with TF or UF TF resin was more effective in the separation and the concentration of gold(III) ions from copper(II) and zinc(II) ions than UF resin. It was seen that sulfur atoms contributed the gold(III) adsorption comparing with oxygen atoms. (C) 2008 Wiley Periodicals, Inc. J Appl Polym Sci 111: 2798-2805, 2009