Selective metal sensor phthalocyanines bearing non-peripheral functionalities: Synthesis, spectroscopy, electrochemistry and spectroelectrochemistry

Kandaz, Mehmet; Yaraşır, Meryem Nilüfer

dc.contributor.authors	Kandaz, M; Yarasir, MN; Koca, A;
dc.date.accessioned	2020-02-24T14:14:16Z
dc.date.available	2020-02-24T14:14:16Z
dc.date.issued	2009
dc.identifier.citation	Kandaz, M; Yarasir, MN; Koca, A; (2009). Selective metal sensor phthalocyanines bearing non-peripheral functionalities: Synthesis, spectroscopy, electrochemistry and spectroelectrochemistry. POLYHEDRON, 28, 262-257
dc.identifier.issn	0277-5387
dc.identifier.uri	https://doi.org/10.1016/j.poly.2008.11.035
dc.identifier.uri	https://hdl.handle.net/20.500.12619/44712
dc.description.abstract	A novel alcohol-soluble ionophore ligand and its non-peripherally tetrasubstituted functional 1,8,15,22-tetrakis(6-hydroxyhexylsulfanyl) metallophthalocyanines M[Pc(alpha-SC(6)H(12)OH)(4)] (M = Cu(II), Zn(II), Co(II); Pc=phthalocyanine) are reported. The aggregation and cation binding behaviors of the phthalocyanine compounds in the presence of soft Ag(I) and Pd(II) metal ions were investigated by using UV-Vis spectroscopy. The new compounds have been characterized by elemental analysis, IR, (1)H, (13)C NMR, UV/Vis spectroscopy, ESI and MALDI-TOF-MS mass spectra. Voltammetric and in-situ spectroelectrochemical studies show that while copper and zinc phthalocyanine complexes give well-defined ring-based reduction and oxidation processes, the cobalt phthalocyanine gives both metal-based and ring-based redox processes which have reversible and diffusion controlled character. (c) 2008 Elsevier Ltd. All rights reserved.
dc.language	English
dc.publisher	PERGAMON-ELSEVIER SCIENCE LTD
dc.subject	Crystallography
dc.title	Selective metal sensor phthalocyanines bearing non-peripheral functionalities: Synthesis, spectroscopy, electrochemistry and spectroelectrochemistry
dc.type	Article
dc.identifier.volume	28
dc.identifier.startpage	257
dc.identifier.endpage	262
dc.contributor.department	Sakarya Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü
dc.contributor.saüauthor	Kandaz, Mehmet
dc.contributor.saüauthor	Yaraşır, Meryem Nilüfer
dc.relation.journal	POLYHEDRON
dc.identifier.wos	WOS:000263480300010
dc.identifier.doi	10.1016/j.poly.2008.11.035
dc.contributor.author	Kandaz, Mehmet
dc.contributor.author	Yaraşır, Meryem Nilüfer