Bromination of 5-methoxyindane: Synthesis of new benzoindenone derivatives and ready access to 7H-Benzo[c]fluoren-7-one skeleton

Tutar, Ahmet

dc.contributor.authors	Tutar, A; Berkil, K; Hark, RR; Balci, M;
dc.date.accessioned	2020-02-24T14:14:10Z
dc.date.available	2020-02-24T14:14:10Z
dc.date.issued	2008
dc.identifier.citation	Tutar, A; Berkil, K; Hark, RR; Balci, M; (2008). Bromination of 5-methoxyindane: Synthesis of new benzoindenone derivatives and ready access to 7H-Benzo[c]fluoren-7-one skeleton. SYNTHETIC COMMUNICATIONS, 38, 1345-1333
dc.identifier.issn	0039-7911
dc.identifier.uri	https://doi.org/10.1080/00397910801916223
dc.identifier.uri	https://hdl.handle.net/20.500.12619/44685
dc.description.abstract	The photobromination of 5-methoxyindane and 5-methoxyindanone was studied at both high and low temperatures. 1,2,3-Tribromo-6-methoxyindene was easily synthesized by photolytic bromination of 5-methoxyindane at low temperature. 1,1,2,3-Tetrabromo-6-methoxyindene was obtained from the photobromination of 5-methoxyindan at 77 degrees C, which could then be easily converted to the 2,3-dibromo-6-methoxyindene by silver-supported hydrolysis. Photochemical bromination of 5-methoxy-1-indanone with N-bromosuccinimide (NBS) gave 3-bromo-6-methoxyindene, which upon thermolysis gave a benzo[c]fluorenone derivative.
dc.language	English
dc.publisher	TAYLOR & FRANCIS INC
dc.subject	Chemistry
dc.title	Bromination of 5-methoxyindane: Synthesis of new benzoindenone derivatives and ready access to 7H-Benzo[c]fluoren-7-one skeleton
dc.type	Article
dc.identifier.volume	38
dc.identifier.startpage	1333
dc.identifier.endpage	1345
dc.contributor.department	Sakarya Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü
dc.contributor.saüauthor	Tutar, Ahmet
dc.relation.journal	SYNTHETIC COMMUNICATIONS
dc.identifier.wos	WOS:000254948900003
dc.identifier.doi	10.1080/00397910801916223
dc.contributor.author	Tutar, Ahmet