Synthesis and properties of copper(II) phthalocyanines with monoazacrown and crown ethers as peripheral substituents

Kandaz, Mehmet

dc.contributor.authors	Kandaz, M; Bekaroglu, O;
dc.date.accessioned	2020-02-24T14:14:00Z
dc.date.available	2020-02-24T14:14:00Z
dc.date.issued	1999
dc.identifier.citation	Kandaz, M; Bekaroglu, O; (1999). Synthesis and properties of copper(II) phthalocyanines with monoazacrown and crown ethers as peripheral substituents. JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 3, 345-339
dc.identifier.issn	1088-4246
dc.identifier.uri	https://hdl.handle.net/20.500.12619/44639
dc.description.abstract	Soluble and less soluble phthalocyaninatocopper(II) derivatives (4a and 4b) were prepared from the corresponding 7-[(4'-benzo-15-crown-5)oyl]-15, 16-dibromo-2,3,6,7,8,9,11,12-octahydro-5H-benzo[e]-12-octahydro-5H-benzo[e]-[1,4,10,13,7] tetraoxaazacyclopentadecine (3a) and 7-(2'-tosylaminoethyl)-15, 16-dibromo-2,3,6,7,8,9,11,12-octahydro-5H-benzo[e]-[1,4,10,13,7] tetraoxaazacyclopentadecine (3b) and CuCN in pyridine. A less soluble novel multifunctionalized scorpiand macrocycle-substituted phthalocyanine (4c) in which an NH2CH2CH2- chain is appended to a monoazacrown ether ring was obtained by detosylation of 4b with concentrated sulfuric acid. Copyright (C) 1999 John Wiley & Sons, Ltd.
dc.language	English
dc.publisher	WORLD SCI PUBL CO INC
dc.subject	Chemistry
dc.title	Synthesis and properties of copper(II) phthalocyanines with monoazacrown and crown ethers as peripheral substituents
dc.type	Article
dc.identifier.volume	3
dc.identifier.startpage	339
dc.identifier.endpage	345
dc.contributor.department	Sakarya Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü
dc.contributor.saüauthor	Kandaz, Mehmet
dc.relation.journal	JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
dc.identifier.wos	WOS:000081257200002
dc.identifier.eissn	1099-1409
dc.contributor.author	Kandaz, Mehmet