dc.contributor.authors |
Pi, Chaoran; Li, Xingxing; Zhang, Xuming; Song, Hao; Zheng, Yang; Gao, Biao; Kizilaslan, Abdulkadir; Chu, Paul K.; Huo, Kaifu |
|
dc.date.accessioned |
2022-12-20T13:25:19Z |
|
dc.date.available |
2022-12-20T13:25:19Z |
|
dc.date.issued |
2022 |
|
dc.identifier.issn |
1613-6810 |
|
dc.identifier.uri |
http://dx.doi.org/10.1002/smll.202201137 |
|
dc.identifier.uri |
https://hdl.handle.net/20.500.12619/99291 |
|
dc.description |
Bu yayının lisans anlaşması koşulları tam metin açık erişimine izin vermemektedir. |
|
dc.description.abstract |
Cost-effective electrocatalysts for the hydrogen evolution reaction (HER) spanning a wide pH range are highly desirable but still challenging for hydrogen production via electrochemical water splitting. Herein, Mo5N6-MoS2 heterojunction nanosheets prepared on hollow carbon nanoribbons (Mo5N6-MoS2/HCNRs) are designed as Mott-Schottky electrocatalysts for efficient pH-universal HER. The in-plane Mo5N6-MoS2 Mott-Schottky heterointerface induces electron redistribution and a built-in electric field, which effectively activates the inert MoS2 basal planes to intrinsically increase the electrocatalytic activity, improve electronic conductivity, and boost water dissociation activity. Moreover, the vertical Mo5N6-MoS2 nanosheets provide more activated sites for the electrochemical reaction and facilitate mass/electrolyte transport, while the tightly coupled HCNRs substrate and metallic Mo5N6 provide fast electron transfer paths. Consequently, the Mo5N6-MoS2/HCNRs electrocatalyst delivers excellent pH-universal HER performances exemplified by ultralow overpotentials of 57, 59, and 53 mV at a current density of 10 mA cm(-2) in acidic, neutral, and alkaline electrolytes with Tafel slopes of 38.4, 43.5, and 37.9 mV dec(-1), respectively, which are superior to those of the reported MoS2-based catalysts and outperform Pt in overall water splitting. This work proposes a new strategy to construct an in-plane heterointerface on the nanoscale and provides fresh insights into the HER electrocatalytic mechanism of MoS2-based heterostructures. |
|
dc.language |
English |
|
dc.language.iso |
eng |
|
dc.relation.isversionof |
10.1002/smll.202201137 |
|
dc.subject |
Chemistry |
|
dc.subject |
Science & Technology - Other Topics |
|
dc.subject |
Materials Science |
|
dc.subject |
Physics |
|
dc.subject |
hydrogen evolution reaction |
|
dc.subject |
in-plane heterojunctions |
|
dc.subject |
molybdenum disulfide |
|
dc.subject |
molybdenum nitride |
|
dc.subject |
Mott-Schottky effect |
|
dc.title |
In-Plane Mott-Schottky Effects Enabling Efficient Hydrogen Evolution from Mo5N6-MoS2 Heterojunction Nanosheets in Universal-pH Electrolytes |
|
dc.contributor.authorID |
Kızılaslan, Abdulkadir/0000-0002-1967-5855 |
|
dc.contributor.authorID |
Chu, Paul K/0000-0002-5581-4883 |
|
dc.contributor.authorID |
HUO, Kaifu/0000-0001-5670-8233 |
|
dc.contributor.authorID |
Pi, Chaoran/0000-0003-4652-2106 |
|
dc.contributor.authorID |
Zheng, Yang/0000-0002-3421-087X |
|
dc.identifier.volume |
18 |
|
dc.relation.journal |
SMALL |
|
dc.identifier.issue |
22 |
|
dc.identifier.doi |
10.1002/smll.202201137 |
|
dc.identifier.eissn |
1613-6829 |
|
dc.contributor.author |
Pi, Chaoran |
|
dc.contributor.author |
Li, Xingxing |
|
dc.contributor.author |
Zhang, Xuming |
|
dc.contributor.author |
Song, Hao |
|
dc.contributor.author |
Zheng, Yang |
|
dc.contributor.author |
Gao, Biao |
|
dc.contributor.author |
Kizilaslan, Abdulkadir |
|
dc.contributor.author |
Chu, Paul K. |
|
dc.contributor.author |
Huo, Kaifu |
|
dc.relation.publicationcategory |
Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı |
|