dc.date.accessioned |
2021-06-08T09:12:01Z |
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dc.date.available |
2021-06-08T09:12:01Z |
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dc.date.issued |
2020 |
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dc.identifier.issn |
0268-2605 |
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dc.identifier.uri |
https://hdl.handle.net/20.500.12619/96173 |
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dc.description |
Scientific and Technological Research Council of Turkey (TUBITAK), Grant/Award Number: MFAG-117F235 |
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dc.description |
Bu yayının lisans anlaşması koşulları tam metin açık erişimine izin vermemektedir. |
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dc.description.abstract |
A series of mixed-ligand M(II) complexes containing 1,10-phenanthroline (phen) and 3-methylpyridine-2-carboxylic acid (3-mpaH) or 6-methylpyridine-2-carboxylic acid (6-mpaH), namely [Co(3-mpa)(2)(phen)]center dot 3H(2)O (1), [Hg(6-mpa)(2)(phen)]center dot 2H(2)O (2), [Mn(6-mpa)(2)(phen)]center dot 2H(2)O (3), [Co(6-mpa)(2)(phen)]center dot H2O (4) and [Ni(6-mpa)(2)(phen)]center dot H2O (5), were synthesized for the first time. Among them, 1 was obtained as single crystals. The structural characterization for 1 was conducted using X-ray diffraction and that for 2-5 using mass spectrometry. The IC50 values for alpha-glucosidase inhibition of 1-5 were obtained as 0.161 to >600 mu M. The spectral properties were also investigated using Fourier transform infrared and UV-visible spectra. Furthermore, to investigate the geometrical parameters, spectral and electronic properties and second- and third-order nonlinear optical parameters for 1-5, density functional calculations were applied. |
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dc.description.sponsorship |
Scientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [MFAG-117F235] |
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dc.language |
English |
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dc.language.iso |
eng |
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dc.publisher |
WILEY |
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dc.relation.isversionof |
10.1002/aoc.5412 |
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dc.rights |
info:eu-repo/semantics/closedAccess |
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dc.subject |
NONLINEAR-OPTICAL-PROPERTIES |
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dc.subject |
DENSITY-FUNCTIONAL THEORY |
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dc.subject |
CRYSTAL-STRUCTURE |
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dc.subject |
AB-INITIO |
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dc.subject |
PICOLINATE COMPLEXES |
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dc.subject |
TRANSITION-METAL |
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dc.subject |
HARTREE-FOCK |
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dc.subject |
ACID |
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dc.subject |
HYPERPOLARIZABILITIES |
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dc.subject |
6-METHYLPICOLINATE |
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dc.title |
Synthesis, spectral properties, in vitro alpha-glucosidase inhibitory activity and quantum chemical calculations of novel mixed-ligand M(II) complexes containing 1,10-phenanthroline |
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dc.type |
Article |
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dc.contributor.authorID |
Kurt, Belma Zengin/0000-0002-4663-5402 |
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dc.contributor.authorID |
Sonmez, Fatih/0000-0001-7486-6374 |
|
dc.contributor.authorID |
Dege, Necmi/0000-0003-0660-4721 |
|
dc.contributor.authorID |
ALTURK, SUMEYYE/0000-0002-8177-2365 |
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dc.identifier.volume |
34 |
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dc.relation.journal |
APPLIED ORGANOMETALLIC CHEMISTRY |
|
dc.identifier.issue |
4 |
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dc.identifier.doi |
10.1002/aoc.5412 |
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dc.identifier.eissn |
1099-0739 |
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dc.contributor.author |
Avci, Davut |
|
dc.contributor.author |
Alturk, Sumeyye |
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dc.contributor.author |
Sonmez, Fatih |
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dc.contributor.author |
Tamer, Omer |
|
dc.contributor.author |
Basoglu, Adil |
|
dc.contributor.author |
Atalay, Yusuf |
|
dc.contributor.author |
Kurt, Belma Zengin |
|
dc.contributor.author |
Dege, Necmi |
|
dc.relation.publicationcategory |
Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı |
|