dc.rights.license |
DOAJ Gold |
|
dc.date.accessioned |
2021-06-03T08:20:31Z |
|
dc.date.available |
2021-06-03T08:20:31Z |
|
dc.date.issued |
2020 |
|
dc.identifier.issn |
1551-7004 |
|
dc.identifier.uri |
www.doi.org/10.24820/ark.5550190.p011.090 |
|
dc.identifier.uri |
https://hdl.handle.net/20.500.12619/95196 |
|
dc.description |
Bu yayın 06.11.1981 tarihli ve 17506 sayılı Resmî Gazete’de yayımlanan 2547 sayılı Yükseköğretim Kanunu’nun 4/c, 12/c, 42/c ve 42/d maddelerine dayalı 12/12/2019 tarih, 543 sayılı ve 05 numaralı Üniversite Senato Kararı ile hazırlanan Sakarya Üniversitesi Açık Bilim ve Açık Akademik Arşiv Yönergesi gereğince açık akademik arşiv sistemine açık erişim olarak yüklenmiştir. |
|
dc.description.abstract |
Cyclitols and their halogen derivatives are important compounds in organic chemistry, and thus their synthesis with high efficiency has gained importance. In this study, BX3-assisted (X=Br or Cl) ring-opening reactions of the mono-epoxide 15 of [(3aR(S),7aS(R))]-2,2-dimethyl-3-tosyl-2,3,3a,6,7,7a-hexahydrobenzo[d]oxazole (12) have been investigated. In BX3-assisted (BBr3 or BCl3) ring-opening processes, this epoxide reacts exclusively via nucleophilic attack at carbon 3a-C of the substrate and such regioselectivity has been exploited in the synthesis of the N-tosyl bromo- and N-tosyl chloro-dihydroconduramines. The structures of the products were established by chemical correlation studies. |
|
dc.description.sponsorship |
Scientific and Technical Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [106T374] |
|
dc.language |
English |
|
dc.language.iso |
İngilizce |
|
dc.publisher |
ARKAT USA INC |
|
dc.relation.isversionof |
10.24820/ark.5550190.p011.090 |
|
dc.rights |
info:eu-repo/semantics/openAccess |
|
dc.subject |
STEREOSPECIFIC SYNTHESIS |
|
dc.subject |
CONDURITOLS |
|
dc.subject |
INOSITOL |
|
dc.subject |
DESIGN |
|
dc.subject |
REGIO |
|
dc.subject |
MUCO |
|
dc.subject |
GALA |
|
dc.subject |
PURE |
|
dc.subject |
Cyclitols |
|
dc.subject |
dihydroconduramines |
|
dc.subject |
halodihydroconduramines |
|
dc.subject |
mono-epoxide |
|
dc.title |
The synthesis and characterization of N-tosyl halodihydroconduramines from corresponding mono-epoxy derivative |
|
dc.type |
Article |
|
dc.identifier.startpage |
105 |
|
dc.identifier.endpage |
113 |
|
dc.relation.journal |
ARKIVOC |
|
dc.identifier.wos |
WOS:000584517600011 |
|
dc.identifier.doi |
10.24820/ark.5550190.p011.090 |
|
dc.identifier.eissn |
1551-7012 |
|
dc.contributor.author |
Kurbanoglu, Namudar Izzet |
|
dc.contributor.author |
Baran, Arif |
|
dc.contributor.author |
Col, Sumeyye |
|
dc.relation.publicationcategory |
Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı |
|